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Chapter 5: Chemical Energetics – Exothermic & Endothermic Reactions

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Embark on a journey into the realm of Chemical Energetics in Chapter 5 of the Cambridge International Education (CIE) IGCSE Chemistry curriculum. This chapter delves into the captivating dynamics of exothermic and endothermic reactions, unraveling the intricacies of energy changes during chemical processes.

Discover the definitions of these reactions, understand their effects on the surroundings, and interpret reaction pathway diagrams that visually depict the fascinating journey of energy within a chemical system

1. Exothermic Reaction

  • Definition: An exothermic reaction is a chemical reaction that releases thermal energy to the surroundings.
  • Effect: This leads to an increase in the temperature of the surroundings as thermal energy is transferred out of the system.

2. Endothermic Reaction

  • Definition: An endothermic reaction is a chemical reaction that absorbs thermal energy from the surroundings.
  • Effect: This results in a decrease in the temperature of the surroundings as thermal energy is taken into the system.

3. Interpretation of Reaction Pathway Diagrams:

  • Exothermic Reaction Pathway:
    • Starting Energy Level: The reactants have a higher energy level.
    • Energy Change: During the reaction, energy is released to the surroundings.
    • Ending Energy Level: The products have a lower energy level than the reactants.
    • Representation: The reaction pathway slopes downward from reactants to products, indicating the release of energy.
  • Endothermic Reaction Pathway:
    • Starting Energy Level: The reactants have a lower energy level.
    • Energy Change: During the reaction, energy is absorbed from the surroundings.
    • Ending Energy Level: The products have a higher energy level than the reactants.
    • Representation: The reaction pathway slopes upward from reactants to products, indicating the absorption of energy.

Explanation:

1. Exothermic Reaction:

  • Example: Combustion reactions, such as burning fuel.
  • Energy Change: Energy is released during bond formation in the products, leading to a net release of thermal energy.
  • Temperature Effect: The surroundings experience an increase in temperature due to the gained thermal energy.
Endothermic Reaction

2. Endothermic Reaction:

  • Example: Dissolving ammonium chloride in water.
  • Energy Change: Energy is absorbed during bond breaking in the reactants, requiring an input of thermal energy.
  • Temperature Effect: The surroundings experience a decrease in temperature as thermal energy is absorbed.

Interpretation of Reaction Pathway Diagrams:

  • Exothermic Reaction Pathway:
    • The reactants have higher potential energy than the products.
    • The difference in energy is released to the surroundings.
    • The reaction pathway is represented as a downward slope.
  • Endothermic Reaction Pathway:
    • The reactants have lower potential energy than the products.
    • Energy is absorbed from the surroundings.
    • The reaction pathway is represented as an upward slope.

Understanding these concepts and their graphical representations is crucial for interpreting and explaining energy changes in chemical reactions at the IGCSE level.

Endothermic & Exothermic Reactions (5.1.1) | CIE IGCSE Chemistry Revision Notes 2023 | Save My Exams

Summary:

Chapter 5 of the CIE IGCSE Chemistry curriculum explores Chemical Energetics, focusing on exothermic and endothermic reactions. Exothermic reactions release thermal energy, leading to a temperature increase, while endothermic reactions absorb energy, causing a temperature decrease. The chapter introduces reaction pathway diagrams, visually depicting energy changes. In exothermic reactions, starting energy surpasses the ending energy, with a downward-sloping pathway indicating energy release.

Conversely, endothermic reactions start with lower energy, and an upward-sloping pathway denotes energy absorption. Real-world examples like combustion reactions and dissolving ammonium chloride illustrate these concepts, offering a foundational understanding of energy dynamics in chemical reactions at the IGCSE level.

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